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Thermal Crystallization

Introduction:

There are two methods for crystallization of high brine: one is thermal crystallization, which is suitable for substances whose temperature has little effect on solubility. The “sunshine dry salt” in coastal areas is the method used. The other one is cooling the hot saturated solution method. This method is applicable to substances with increased temperature and increased solubility.
Detailed Introduction

There are two methods for crystallization of high brine: one is thermal crystallization, which is suitable for substances whose temperature has little effect on solubility. The “sunshine dry salt” in coastal areas is the method used. The other one is cooling the hot saturated solution method. This method is applicable to substances with increased temperature and increased solubility.For example, in the salt lakes of the northern region, there is no crystal on the lake surface when the temperature is high in summer.When the temperature is lowered in winter, the mirabilite and other substances are separated from the salt lake.


Evaporation Thermal Crystallization

Theory

Evaporating the solvent will cause the solution to change from unsaturated to saturated.If evaporation continues,the excess solute will crystallize out.This is called evaporative crystallization. For example, when there is more NaCl than KNO3 in the mixture of NaCl and KNO3, this method can be adopted. NaCl will be separated first, and KNO3 later.

When the solubility increases with the increase of temperature by observing the solubility curve,, the solute is steep rise type.On the contrary it is slow rise type.

When a steep rise type is mixed with a slow rise type, cooling crystallization can be adopted to separate the steep rise substance.However, evaporation crystallization method separate the slow rise substance.Evaporation crystallization is suitable for substances whose solubility does not change much with temperature, such as sodium chloride.

Potassium nitrate is a steep type, and sodium chloride is a slow rise type. Therefore, it is possible to separate sodium chloride by evaporation crystallization, or to separate potassium nitrate by cooling crystallization.


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