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Advanced Oxidation

Introduction:

As a new technology for the treatment of refractory pollutants, advanced oxidation technology has the characteristics of producing a large amount of very active hydroxyl radicals (·OH), strong oxidizing ability, cleaned degradation products, easy control of reaction process and flexible processing. At present, the advanced oxidation treatment methods commonly used are Fenton and Fenton-like oxidation and ozone oxidation.
Detailed Introduction

As a new technology for the treatment of refractory pollutants, advanced oxidation technology has the characteristics of producing a large amount of very active hydroxyl radicals (·OH), strong oxidizing ability, cleaned degradation products, easy control of reaction process and flexible processing. At present, the advanced oxidation treatment methods commonly used are Fenton and Fenton-like oxidation and ozone oxidation.


1)Ozone Oxidation Method

Ozone oxidation method, including UV/O3, H2O2/O3, UV/H2O2/O3, etc., improves oxidation rate and efficiency.But due to low solubility of ozone in water, low utilization of ozone, low ozone generation rate, and high energy consumption,the application of ozone oxidation technology is restricted.For Fenton method or Fenton method, it is a complex chain reaction of hydrogen peroxide under the action of catalyst iron (II) salt or transition metal under acidic conditions. It produces a hydroxyl radical (·OH) with strong oxidizing ability, and its oxidizing ability exceeds that of superoxide (·O 2- ) or ozone (O3), which is the most oxidizing in active oxygen.This technology is widely used in the complex wastewater treatment.


Ozone oxidation process sketch


2)Fenton oxidation

The Fenton oxidation method is a wastewater treatment method to carry out chemical oxidation with H2O2,taking Fe2+ as a catalyst under the condition of pH=2-5. A system composed of Fe2+/H2O2 is called a Fenton reagent. The reaction mechanism is that Fe2+ and Fe3+ react with H2O2 to form a strong oxidizing hydroxyl radical, which will react with the refractory organic matter in the water to form organic radical.The structure of the refractory organic matter is destroyed and the oxidative decomposition is realized.


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